METALLOTROPIC η5-η6 REARRANGEMENT IN INDENYLTRICARBONYL COMPLEXES OF MANGANESE AND RHENIUM IN AN ACID MEDIUM

DOI: 10.1016/0022-328X(85)87195-3

Source and publish data:

Journal of Organometallic Chemistry p. 363 - 368 (1985)

Update date:2022-07-31

Topics:

Authors:

Yezernitskaya, M. G.

Lokshin, B. V.

Zdanovich, V. I.

Lobanova, I. A.

Kolobova, N. E.

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Article abstract of DOI:10.1016/0022-328X(85)87195-3

An Ir spectroscopic study has shown that the reactions of (η⁵-C9H7)M(CO)3 (M=Mn, Re) and (η⁵-C13H9)Mn(CO)3 with AlCl3*HCl and FSO3H involve metallotropic η⁵ -> η⁶ rearrangement in which the metal carbonyl group

Full text of DOI:10.1016/0022-328X(85)87195-3

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Product name:[C₉H₈Mn(CO)3]⁽¹⁺⁾*BF₄^(1-)=[C₉H₈Mn(CO)3]BF₄

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