Synthesis of iodoalkylidene lactones from alkenes

DOI: 10.1016/S0040-4020(01)85740-9

Source and publish data:

Tetrahedron p. 4229 - 4252 (1993)

Update date:2022-09-26

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Authors:

Haaima Haaima

Lynch Lynch

Routledge

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Article abstract of DOI:10.1016/S0040-4020(01)85740-9

Alkenes are reality transformed into iodo acetylenic esters by addition of acetylenic acids in the presence of a source of iodonium ion. A subsequent free-radical cyclisation induced by dibenzoyl peroxide leads to (E)-iodoalkylidene butyrolactones.

Full text of DOI:10.1016/S0040-4020(01)85740-9

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