Studies on the reactivity of rhodium(I) dimers with salen as the bridging ligand

DOI: 10.1016/0022-328X(88)80248-1

Source and publish data:

Journal of Organometallic Chemistry p. 201 - 208 (1988)

Update date:2022-09-26

Topics: applications Mechanistic Studies Ligand Exchange Catalytic Activity Structural Variations

Authors:

Pasini, Alessandro

Caldirola, Cristina

Colombo, Anna

Ghilotti, Manuela

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Article abstract of DOI:10.1016/0022-328X(88)80248-1

Reaction of <(Rh(CO)2)2salen> (I) with an equimolar amount of MeI or I2 gives green, weakly paramagnetic, little characterized materials.Use of an excess of the MeI or I2 reagent leads to decomposition.Reactions of <(Rh(CO)L)2salen> (II) (L = PPh3), with

Full text of DOI:10.1016/0022-328X(88)80248-1

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