Neighbouring Group Effects on Rates of Thermolysis of 4-Azidothiazoles

DOI: 10.1016/S0040-4020(97)00638-8

Source and publish data:

Tetrahedron p. 9657 - 9668 (1997)

Update date:2022-08-04

Topics:

Authors:

Ceulemans, Erik

Vercauteren, Karin

Dyall, Leonard K.

Buelens, Dirk

Dehaen, Wim

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Article abstract of DOI:10.1016/S0040-4020(97)00638-8

Rate measurements for thermolysis of 4-azidothiazoles in p-xylene solution have identified neighbouring group effects from nitro (19-fold rate increase), phenyliminomethyl (16), formyl (4.5) and acetyl (2.2) substituents in the 5-position. These effects a

Full text of DOI:10.1016/S0040-4020(97)00638-8

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