
Tetrahedron p. 6143 - 6152 (1988)
Update date:2022-08-05
Topics:
Hendry, David
Hough, Leslie
Richardson, Anthony C.
Enantiospecific synthesis of (6S,7R,8R,8aR)-6,7,8-trihydroxyindolizidine (1-deoxy-castanospermine) (3) is described from readily available D-glucose, where the key step involves oxidative bromination of a benzylidene acetal to afford 8-azido-3-O-benzoyl-5
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