Diels-Alder Reaction of Dimethyl Acetoxymethylenemalonate with 3,4-Dialkoxyfurans and the Utility of Its Adducts in the Stereospecific Synthesis of Lyxopyranosyl C-Glycosides

Article abstract of DOI:10.1246/cl.1987.2257

Dimethyl lyxopyranosylmalonates were synthesized in stereospecific manner from the adducts obtained from Diels-Alder reaction of 3,4-dialkoxyfurans and dimethyl acetoxymethylenemalonate, through retrograde aldol C-C bond fission under reductive condition as a key step.