Diels-Alder Reaction of Dimethyl Acetoxymethylenemalonate with 3,4-Dialkoxyfurans and the Utility of Its Adducts in the Stereospecific Synthesis of Lyxopyranosyl C-Glycosides

DOI: 10.1246/cl.1987.2257

Source and publish data:

Chemistry Letters p. 2257 - 2260 (1987)

Update date:2022-07-30

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Authors:

Katagiri, Nobuya

Akatsuka, Hidenori

Haneda, Toru

Kaneko, Chikara

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Article abstract of DOI:10.1246/cl.1987.2257

Dimethyl lyxopyranosylmalonates were synthesized in stereospecific manner from the adducts obtained from Diels-Alder reaction of 3,4-dialkoxyfurans and dimethyl acetoxymethylenemalonate, through retrograde aldol C-C bond fission under reductive condition as a key step.

Full text of DOI:10.1246/cl.1987.2257

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