New radical homoallylation reactions

DOI: 10.1055/s-2003-41011

Source and publish data:

Synlett p. 1627 - 1630 (2003)

Update date:2022-08-04

Topics:

Authors:

Ouvry, Gilles

Zard, Samir Z.

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Article abstract of DOI:10.1055/s-2003-41011

Xanthate addition to 3-aryl-4-methanesulfonylbutene and structurally related derivatives triggers a cascade involving aryl migration and elimination of a sulfonyl radical, the result being an overall homoallylation of the initial radical. Other slow migra

Full text of DOI:10.1055/s-2003-41011

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