Asymmetric Induction by Chiral Silicon. Synthesis and Electrophilic Reactivity towards Dienes and Carbanions of R-(-)-Methyl-α-naphthyl-phenylsilyl Phenyl Thioketone

DOI: 10.1039/c39880000365

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 365 - 367 (1988)

Update date:2022-08-02

Topics:

Authors:

Bonini, Bianca F.

Mazzanti, Germana

Zani, Paolo

Maccagnani, Gaetano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000365

The title compound was prepared by acid catalysed reaction of the corresponding ketone with hydrogen sulphide, and its ability to transfer chirality to the carbon α to silicon in reactions with buta-1,3-diene and methyl-lithium was tested; good levels of

Full text of DOI:10.1039/c39880000365

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:R-(-)-methyl-α-naphthyl-phenylsilyl phenyl thioketone

Cas No:115691-12-8

R&D Labs maybe for 115691-12-8

Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd

Contact:+86-517-86283327

Address:9 North Hantai Road, Huaian, China
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
Hangzhou Dingyan Chem Co., Ltd

website:http://www.dingyanchem.com

Contact:86-571-87157530

Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA

Relevant to this article

Novel charge-transfer chromophores featuring imidazole as Π-linkage

Doi:10.3987/COM-08-11609
(2009)
Structure of Hydroazulenoid Diterpens from a Marine Alga and Their Absolute Configuration Based on Circular Dichroism

Doi:10.1021/jo00255a025
(1988)
Heterocyclic analogs of nucleosides: Synthesis and biological evaluation of some 1-(3-thianyl)uracil and 9-(3-thianyl)adenine derivatives

Doi:10.1139/v94-032
(1994)
Transition Metal Dienyls in Organic Synthesis. Dienyl Transfer Reactions from Zirconium to Phosphorus and to Boron

Doi:10.1021/jo00253a052
(1988)
Phosphinoferrocenyl carboxamides bearing glycine pendant groups: Synthesis, palladium(II) complexes, and catalytic use in polar and aqueous reaction media

Doi:10.1021/om900209j
(2009)
Selective iron-catalyzed oxidation of benzylic and allylic alcohols

Doi:10.1002/adsc.201100210
(2011)

Article Doi