Asymmetric Induction by Chiral Silicon. Synthesis and Electrophilic Reactivity towards Dienes and Carbanions of R-(-)-Methyl-α-naphthyl-phenylsilyl Phenyl Thioketone

DOI: 10.1039/c39880000365

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 365 - 367 (1988)

Update date:2022-08-02

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Authors:

Bonini, Bianca F.

Mazzanti, Germana

Zani, Paolo

Maccagnani, Gaetano

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Article abstract of DOI:10.1039/c39880000365

The title compound was prepared by acid catalysed reaction of the corresponding ketone with hydrogen sulphide, and its ability to transfer chirality to the carbon α to silicon in reactions with buta-1,3-diene and methyl-lithium was tested; good levels of

Full text of DOI:10.1039/c39880000365

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