Liebigs Annalen p. 1811 - 1821 (1996)
Update date:2022-08-04
Topics:
Michel, Tycho
Kirschning, Andreas
Beier, Christian
Braeuer, Nico
Schaumann, Ernst
Adiwidjaja, Gunadi
1,3-Functionalized cyclopentanes, -hexanes and -heptanes are obtained by addition of lithiated silyldithioacetals 7 to epoxyhomoallyl tosylates 4-6. The reaction involves a cascade of epoxide ring opening, of Brook 1,4-rearrangement and tosylate substitut
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