Tetrahedron Letters p. 4861 - 4864 (1987)
Update date:2022-07-29
Topics:
Carreno, M.C.
Ruano, J.L.Garcia
Rubio, A.
The reaction of cyclohexanone with (S)-(-)-menthyl-p-toluenesulfinate in the presence of i-Pr2NMgBr yields a mixture of enantiomerically pure 2-p-tolylsulfinylcyclohexanone diastereoisomers.Their stereoselective reduction to chiral hydroxysulfoxides is also reported.
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