THE TOTAL SYNTHESIS OF (+)-PHYLLANTHOSTATIN 2

DOI: 10.1016/S0040-4039(00)96788-1

Source and publish data:

Tetrahedron Letters p. 5591 - 5594 (1987)

Update date:2022-09-26

Topics:

Authors:

Smith, Amos B. III

Hale, Karl J.

Vaccaro, Henry A.

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Article abstract of DOI:10.1016/S0040-4039(00)96788-1

The first total synthesis of the antitumor glycoside phyllanthostatin 2 (3) is reported utilizing a Mitsunobu glycosidation protocol to unite the disaccharide and aglycone moieties.

Full text of DOI:10.1016/S0040-4039(00)96788-1

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Product name:1-O-phyllanthocinoyl 4,6-bis-O-(chloroacetyl)-3-O-acetyl-2-O-(2,4-bis-O-(chloroacetyl)-3-O-acetyl-6-deoxy-β-D-glucopyranosyl)-β-D-glucopyranoside

Cas No:116113-83-8

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