Stereochemistry of Conjugate Addition to 4- and 5-Substituted α,β-Unsaturated δ-Lactones

DOI: 10.1039/c39870001472

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1472 - 1474 (1987)

Update date:2022-08-02

Topics:

Authors:

Fleming, Ian

Reddy, N. Laxma

Takaki, Ken

Ware, Anne C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001472

Conjugate addition, especially of the phenyldimethylsilylcuprate reagent, to 4- and 5-substituted α,β-unsaturated δ-lactones <(5) and (18)> is highly selective for the formation of the trans-products <(6), (7), (9), (10), and (19)>, the silicon-containing

Full text of DOI:10.1039/c39870001472

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2H-Pyran-2-one, 4-(dimethylphenylsilyl)tetrahydro-6-propyl-, trans-

Cas No:116159-62-7

R&D Labs maybe for 116159-62-7

Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Hefei EnliPharma Tecnology Co.,Ltd

Contact:0086-551-66399836

Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei
Anhui Jiatiansen Agrochemical Co.,Ltd

Contact:15366811918

Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province

Relevant to this article

Freezing of Equilibrium of 1,2,4-Triazole by Complex Formation with 1,1-Di(2,4-dimethylphenyl)but-2-yn-1-ol, and X-Ray Crystal Structure of the Complex

Doi:10.1246/cl.1987.2317
(1987)
Regioselective Opening of Epoxides and Ethers by (Trialkylsilyl)manganese Pentacarbonyl Complexes. A General Strategy for the Synthesis of Spiroketal Lactone and Cyclopentenone Derivatives

Doi:10.1021/jo00255a051
(1988)
Synthesis of tweezer type receptors for colorimetric detection of cyanide ions

Doi:10.1007/s10847-016-0593-4
(2016)
Doi:10.1246/bcsj.34.1334
(1961)
PENTACO-ORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: ASYMMETRIC REDUCTION OF CARBONYL COMPOUNDS WITH HYDROSILANES CATALYZED BY CHIRAL BASES

Doi:10.1016/0040-4039(88)80024-8
(1988)
Doi:10.1002/macp.1956.020180121
(1956)

Article Doi