Stereochemistry of Conjugate Addition to 4- and 5-Substituted α,β-Unsaturated δ-Lactones

DOI: 10.1039/c39870001472

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1472 - 1474 (1987)

Update date:2022-08-02

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Authors:

Fleming, Ian

Reddy, N. Laxma

Takaki, Ken

Ware, Anne C.

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Article abstract of DOI:10.1039/c39870001472

Conjugate addition, especially of the phenyldimethylsilylcuprate reagent, to 4- and 5-substituted α,β-unsaturated δ-lactones <(5) and (18)> is highly selective for the formation of the trans-products <(6), (7), (9), (10), and (19)>, the silicon-containing

Full text of DOI:10.1039/c39870001472

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