Journal of the Chemical Society, Dalton Transactions p. 1561 - 1564 (1988)
Update date:2022-07-29
Topics:
Blake, Alexander J.
Reid, Gillian
Schroeder, Martin
Reaction of RhCl3*3H2O with one molar equivalent of tmc (1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) in refluxing MeOH affords the complex cation a crystallographic mirror plane.The single-crystal X-ray structure of the octahedral complex shows the chloride ions mutually trans to one another, Rh-Cl 2.355(3) and 2.362(3) Angstroem, with the tetra-aza macrocycle adopting an RRSS conformation with two methyl groups lying above, and two methyl groups lying below the RhN4 plane a quasi-reversible RhIII-RhII redox couple at E1/2=-0.99 V vs.
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