Journal of the American Chemical Society p. 6272 - 6273 (1988)
Update date:2022-08-03
Topics:
Kurosawa, Hideo
Ohnishi, Hiroaki
Emoto, Mitsuhiro
Kawasaki, Yoshikane
Murai, Shinji
We report a novel finding that the coupling of allyl and aryl groups on Ni is much more facile in an μ3-allyl form with 18-electron configuration than in both a 16-electron μ3-allyl counterpart and a 16-electron μ1-allyl isomer.This trend seems of particular relevance to the origin of some unique ligand and metal effects upon reactivity and selectivity in catalyses.
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