An Unusually Lower Barrier to Reductive Elimination of an 18-Electron μ3-Allyl(organo)nickel(II) Complex Than Those of a 16-Electron μ3-Allyl Counterpart and a 16-Electron μ1-Allyl Isomer

DOI: 10.1021/ja00226a067

Source and publish data:

Journal of the American Chemical Society p. 6272 - 6273 (1988)

Update date:2022-08-03

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Authors:

Kurosawa, Hideo

Ohnishi, Hiroaki

Emoto, Mitsuhiro

Kawasaki, Yoshikane

Murai, Shinji

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Article abstract of DOI:10.1021/ja00226a067

We report a novel finding that the coupling of allyl and aryl groups on Ni is much more facile in an μ³-allyl form with 18-electron configuration than in both a 16-electron μ³-allyl counterpart and a 16-electron μ¹-allyl isomer.This trend seems of particular relevance to the origin of some unique ligand and metal effects upon reactivity and selectivity in catalyses.

Full text of DOI:10.1021/ja00226a067

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