Reaction of Thioaldehydes with 5-Alkoxyoxazoles: A Route to 3-Thiazolines

DOI: 10.1021/jo00255a004

Source and publish data:

Journal of Organic Chemistry p. 4663 - 4667 (1988)

Update date:2022-07-29

Topics:

Authors:

Vedejs, E.

Fields, S.

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Article abstract of DOI:10.1021/jo00255a004

Generation of thioaldehydes 4 by photolysis of 15 or by thermolysis of 9 in the presence of oxazoles 2 or 3 affords 7 or 8, respectively.Thermally generated thioacetone reacts similarly to give 16 and 17.A mechanism involving an unstable Diels-Alder adduct 5 is most likely.

Full text of DOI:10.1021/jo00255a004

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