REACTION OF BUTYLLITHIUM WITH BENZYLIDENE ACETALS OF ALDOPYRANOSIDES AND 1,5-ANHYDROALDITOLS

DOI: 10.1016/0008-6215(88)85099-7

Source and publish data:

Carbohydrate Research p. 305 - 312 (1988)

Update date:2022-09-26

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Authors:

Horton, Derek

Weckerle, Wolfgang

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Article abstract of DOI:10.1016/0008-6215(88)85099-7

Under suitable conditions, butyllithium selectively cleaves 5-membered benzylidene acetals (1,3-dioxolane ring) leaving the 6-membered analogs (1,3-dioxane ring) intact in aldopyranoside and 1,5-anhydroalditol derivatives.The usual course of the reaction

Full text of DOI:10.1016/0008-6215(88)85099-7

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