REACTION OF BUTYLLITHIUM WITH BENZYLIDENE ACETALS OF ALDOPYRANOSIDES AND 1,5-ANHYDROALDITOLS

DOI: 10.1016/0008-6215(88)85099-7

Source and publish data:

Carbohydrate Research p. 305 - 312 (1988)

Update date:2022-09-26

Topics:

Authors:

Horton, Derek

Weckerle, Wolfgang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0008-6215(88)85099-7

Under suitable conditions, butyllithium selectively cleaves 5-membered benzylidene acetals (1,3-dioxolane ring) leaving the 6-membered analogs (1,3-dioxane ring) intact in aldopyranoside and 1,5-anhydroalditol derivatives.The usual course of the reaction

Full text of DOI:10.1016/0008-6215(88)85099-7

Products guided by the article

Product name:1,5-anhydro 2,3:4,6-di-O-benzylidene-D-mannitol

Cas No:116500-81-3

R&D Labs maybe for 116500-81-3

Li's chemicals

Contact:+86-15850770348

Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Suzhou Howsine Biological Technology Co.,Ltd(expird)

website:http://www.howsine.com

Contact:86-512-67262751

Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
Tradlon Chemical Co., Ltd.

Contact:+86-710-3516804

Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei

Relevant to this article

Remote controlled nucleophilicity, 2: Lithiated C(α)-substituted 4-methylpyridines

Doi:10.1055/s-1991-28423
(1991)
An environmentally benign TEMPO-catalyzed efficient alcohol oxidation system with a recyclable hypervalent iodine(III) reagent and its facile preparation

Doi:10.1055/s-0028-1087850
(2009)
Anionic polymerization of p-pentamethyldisilyl-, p-heptamethyltrisilyl-, and p-nonamethyltetrasilylstyrenes

Doi:10.1021/ma021742a
(2003)
New indolo[3,2-b]carbazole derivatives for field-effect transistor applications

Doi:10.1039/b900271e
(2009)
A facile synthesis of 1,3,4-trisubstituted isoquinolines

Doi:10.1016/j.tetlet.2009.04.040
(2009)
Synthesis and Cardiac Electrophysiological Activity of Aryl-Substituted Derivatives of the Class III Antiarrhythmic Agent Sematilide. Potential Class I/III Agents

Doi:10.1021/jm00164a025
(1990)

Article Doi