The Journal of Organic Chemistry
Article
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Figure 6. Comparison of conversion measured by heat flow to the
conversion measured by FRIT for the reaction in Scheme 4. Reaction
conditions: [6]0 = 66.7 mM, [7]0 = 100 mM, [1]total = 3.335 mM.
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Figure 7. Comparison of conversion measured by heat flow to the
conversion measured by FRIT for the reaction in Scheme 5. Reaction
conditions: [10]0 = 75 mM, [1]total = 3 mM.
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ASSOCIATED CONTENT
* Supporting Information
Kinetic data and computational data. The Supporting
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S
(21) Cho, B.; Tan, C.-H.; Wong, M. W. J. Org. Chem. 2012, 77,
6553−6562.
AUTHOR INFORMATION
Corresponding Authors
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(22) (a) Blackmond, D. G. Angew. Chem. 2005, 117, 4374−4393;
Angew. Chem., Int. Ed. 2005, 44, 4302−4320. (b) Mathew, J. S.;
Klussmann, M.; Iwamura, H.; Valera, F.; Futran, A.; Emanuelsson, E.
A. C.; Blackmond, D. G. J. Org. Chem. 2006, 71, 4711−4722.
(c) Rosner, T.; Le Bars, J.; Pfaltz, A.; Blackmond, D. G. J. Am. Chem.
Soc. 2001, 123, 1848−1855. (d) Singh, U. K.; Strieter, E. R.;
Blackmond, D. G.; Buchwald, S. L. J. Am. Chem. Soc. 2002, 124,
14104−14114. (e) Nielsen, L. P. C.; Stevenson, C. P.; Blackmond, D.
G.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 1360−1362.
(f) Mathew, S. P.; Gunathilagan, S.; Roberts, S. M.; Blackmond, D. G.
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Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
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We gratefully acknowledge the financial support by grants from
NTU (M4080946.110, M4081324.110, RG 6/12
M4011018.110, and M4011372.110) and NUS (R-143-000-
481-112).
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2009, 131, 7212−7213.
(25) Wong, M. W.; Ng, A. M. E. Aust. J. Chem. 2014, 67, 1100−1109.
(26) Huang, D. F.; Qin, S.; Hu, C. W. Org. Biomol. Chem. 2011, 9,
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