Asymmetric Diels-Alder Reaction by the Use of a Chiral Titanium Catalyst with Molecular Sieves 4A. Remarkable Solvent Effect on the Enantioselectivity

DOI: 10.1246/cl.1987.2409

Source and publish data:

Chemistry Letters p. 2409 - 2412 (1987)

Update date:2022-08-04

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Authors:

Narasaka, Koichi

Inoue, Masayuki

Yamada, Tohru

Sugimori, Jun

Iwasawa, Nobuharu

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Article abstract of DOI:10.1246/cl.1987.2409

A remarkable effect of solvent on the enantioselectivity was observed in the asymmetric Diels-Alder reaction of 3-(2-alkenoyl)-1,3-oxazolidin-2-ones and dienes catalyzed by a chiral titanium reagent, and the Diels-Alder adducts were obtained in high enant

Full text of DOI:10.1246/cl.1987.2409

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