CHIRAL CATALYSTS FOR THE ENANTIOSELECTIVE ADDITION OF ORGANOMETALLIC REAGENTS TO ALDEHYDES

DOI: 10.1016/S0040-4039(00)96695-4

Source and publish data:

Tetrahedron Letters p. 5233 - 5236 (1987)

Update date:2022-08-04

Topics:

Authors:

Corey, E. J.

Hannon, Francis J.

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Article abstract of DOI:10.1016/S0040-4039(00)96695-4

A mechanistic model for the enantioselective addition of diethylzinc to benzaldehyde with chiral tridentate lithium complexes as catalysts correctly predicts the observed direction of enantioselectivity which occurs at levels of 85-95percent ee.

Full text of DOI:10.1016/S0040-4039(00)96695-4

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