Tetrahedron p. 1603 - 1608 (1988)
Update date:2022-07-31
Topics:
Moriarty, Robert, M.
Vaid, Radhe K.
Ravikumar, Vasulinga T.
Vaid, Beena K.
Hopkins, Thomas E.
Hypervalent iodine oxidation of β-diketones and β-ketoesters with iodosobenzene-boron trifluoride etherate in chloroform using appropriate nucleophiles results in α-functionalization.Benzoylacetone on reaction with iodosobenzene or iodosobenzene boron trifluoride-etherate in methanol yields α-methoxyacetophenone (9) and methyl phenylacetate (10).The possible mechanisms for these reactions are discussed.
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Doi:10.1246/bcsj.61.2025
(1988)Doi:10.1016/S0040-4039(01)83013-6
(1981)Doi:10.1016/S0040-4039(00)61830-0
(1987)Doi:10.1007/s10593-006-0009-2
(2005)Doi:10.1021/jo00376a108
(1986)Doi:10.1021/ja803627x
(2008)
