Journal of the Chemical Society. Chemical communications p. 1177 - 1179 (1987)
Update date:2022-08-03
Topics:
Fleming, Ian
Kindon, Nicholas D.
The conjugate addition of the phenyldimethylsilyl-cuprate reagent to cinnamate and crotonate esters and amides of various known chiral auxiliaries is diastereoselective, making available β-silylesters of high enantiomeric excess; the sense of the diastereoselectivity is anomalously different from established precedent in the case of silyl-cuprate addition to the cinnamate ester (1, R = Ph, R* = d).
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