REARRANGEMENT APPROACH TO THE FORMAL DISPLACEMENT OF THE BRIDGEHEAD METHOXYL GROUP OF BICYCLO(3.2.2)NON-6-EN-2-ONES WITH ALKYL, ALKENYL, AND ARYL GROUPS

DOI: 10.1016/S0040-4039(01)80855-8

Source and publish data:

Tetrahedron Letters p. 5069 - 5072 (1985)

Update date:2022-08-04

Topics:

Authors:

Uyehara, Tadao

Yamada, Jun-ichi

Kato, Tadahiro

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Article abstract of DOI:10.1016/S0040-4039(01)80855-8

A preferential transformation of the C2-substituted 1-methoxybicyclo(3.2.2)non-6-en-2-ols, derived from 1-methoxybicyclo(3.2.2)non-6-en-2-ones into the C1-substituted bicyclo(3.2.2)non-6-en-2-ones was accomplished by utilizing TsOH in toluene (85 deg C) o

Full text of DOI:10.1016/S0040-4039(01)80855-8

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