Synthesis of an Aromatic Sesquiterpene, (+/-)-Cuparene, via Construction of a Quaternary Carbon Centre by an Intramolecular Carbenoid Displacement Reaction

DOI: 10.1039/c39850001324

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1324 - 1325 (1985)

Update date:2022-07-29

Topics:

Authors:

Kametani, Tetsuji

Kawamura, Kuniaki

Tsubuki, Masayoshi

Honda, Toshio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001324

The synthesis of (+/-)-cuparene (11), which includes as the key step an intramolecular carbenoid displacement reaction at the benzylic position of a benzyl sulphide derivative, is described.

Full text of DOI:10.1039/c39850001324

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:6-oxo-6-(p-tolyl)hexanal

Cas No:117421-36-0

R&D Labs maybe for 117421-36-0

Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China

Relevant to this article

Competing pathways in the photo-Favorskii rearrangement and release of esters: Studies on fluorinated p-hydroxyphenacyl-caged GABA and glutamate phototriggers

Doi:10.1021/jo900139h
(2009)
Ferric Heme-Nitrosyl Complexes: Kinetically Robust or Unstable Intermediates?

Doi:10.1021/acs.inorgchem.7b01493
(2017)
Stereoselective synthesis of anti-N-protected 3-amino-1,2-epoxides by nucleophilic addition to N-tert-butanesulfinyl imine of a glyceraldehyde synthon

Doi:10.1021/jo900643b
(2009)
Multiple silyl exchange reactions: A way to spirooligosilanes

Doi:10.1021/om900287c
(2009)
Radical metalloids with N-heterocyclic carbene and phenanthroline ligands: Synthesis, properties, and cross-coupling reaction of [(nitronyl nitroxide)-2-ido]metal complexes with aryl halides

Doi:10.1246/bcsj.20180033
(2018)
Development of simple firefly luciferin analogs emitting blue, green, red, and near-infrared biological window light

Doi:10.1016/j.tet.2013.03.050
(2013)

Article Doi