72-76 Valence Electron Clusters: An Extension of the 16-18 Electron Rule. Synthesis, Crystal Structure, and Solution Dynamics of the Trigonal-Bipyramidal Pentanuclear Clusters (2-) and (2-)

DOI: 10.1021/ja00183a027

Source and publish data:

Journal of the American Chemical Society p. 165 - 173 (1989)

Update date:2022-07-29

Topics:

Authors:

Fumagalli, Alessandro

Pergola, Roberto Della

Bonacina, Fabio

Garlaschelli, Luigi

Moret, Massimo

Sironi, Angelo

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Article abstract of DOI:10.1021/ja00183a027

The 76 CVE (cluster valence electron) species (2-) (1), obtained by the reductive carbonylation of a mixture of Na2PtCl6 and IrCl3*xH2O or Ir4(CO)12, is in equilibrium with the 72 CVE species (2-) (2) through the dissociation-ass

Full text of DOI:10.1021/ja00183a027

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