Rongalite promoted highly regioselective synthesis of β-hydroxy sulfides by ring opening of epoxides with disulfides

DOI: 10.1016/j.tet.2009.04.085

Source and publish data:

Tetrahedron p. 5240 - 5243 (2009)

Update date:2022-07-31

Topics:

Authors:

Guo, Wenxue

Chen, Jiuxi

Wu, Dengze

Ding, Jinchang

Chen, Fan

Wu, Huayue

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Article abstract of DOI:10.1016/j.tet.2009.04.085

Rongalite promotes cleavage of disulfides generating thiolate anions that then undergo facile ring opening of epoxides in the presence of K₂CO₃ to afford α-addition products 3 with good to excellent yields. The important f

Full text of DOI:10.1016/j.tet.2009.04.085

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