Formation de liaison C-C par couplage reducteur d'ions carbeniums arene chrome tricarbonyle

DOI: 10.1016/0022-328X(87)87164-4

Source and publish data:

Journal of Organometallic Chemistry p. 143 - 152 (1987)

Update date:2022-07-31

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Authors:

Top, Siden

Jaouen, Gerard

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Article abstract of DOI:10.1016/0022-328X(87)87164-4

The Grignard reagent n-BuMgBr reacts with arenetricarbonylchromium carbeniums ions by two competing mechanism; nucleophilic attack leading to alkylation products, and electron transfer giving rise to dimeric compounds.

Full text of DOI:10.1016/0022-328X(87)87164-4

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