Solvation and steric effects on electrophilic reactivity of ethylenic compounds. 2. Kinetic criteria for nucleophilic assistance and return in bromination

DOI: 10.1021/ja00009a032

Source and publish data:

Journal of the American Chemical Society p. 3440 - 3446 (1991)

Update date:2022-07-29

Topics:

Authors:

Ruasse, Marie-Fran?ois

Motallebi, Shahrokh

Galland, Bernard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00009a032

Three kinetic criteria, m_Br, R (k_aqEtOH/k_AcOH)_Y, and KSIE (kinetic solvent isotope effect), are used to estimate the magnitude of the electrophilic and nucleophilic involvement of protic solvents and the occurre

Full text of DOI:10.1021/ja00009a032

Products guided by the article

Product name:1-phenyl-2-ethoxy-3-bromopropane

Cas No:117506-42-0

R&D Labs maybe for 117506-42-0

Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China

Relevant to this article

N-heterocyclic carbene boryl radicals: A new class of boron-centered radical

Doi:10.1021/ja904103x
(2009)
(+)-Rimocidin synthetic studies: Construction of the C(1-27) aglycone skeleton

Doi:10.1021/jo900765p
(2009)
Pd-catalyzed cross-coupling of allylsilane-vinylcopper species with aryl and vinyl halides: the first total synthesis of (-)-nomadone

Doi:10.1016/j.tet.2009.01.118
(2009)
Design, synthesis, and biological evaluation of 16-substituted 4-azasteroids as tissue-Selective Androgen Receptor Modulators (SARMs)

Doi:10.1021/jm900880r
(2009)
Heteroleptic arene ruthenium complexes based on meso-substituted dipyrrins: Synthesis, structure, reactivity, and electrochemical studies

Doi:10.1021/ic9000957
(2009)
Concise synthesis of 2, 3-diarylpyrimido[1,2-α]benzimidazole based on isoflavones

Doi:10.1021/cc900064q
(2010)

Article Doi