Solvation and steric effects on electrophilic reactivity of ethylenic compounds. 2. Kinetic criteria for nucleophilic assistance and return in bromination

DOI: 10.1021/ja00009a032

Source and publish data:

Journal of the American Chemical Society p. 3440 - 3446 (1991)

Update date:2022-07-29

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Authors:

Ruasse, Marie-Fran?ois

Motallebi, Shahrokh

Galland, Bernard

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Article abstract of DOI:10.1021/ja00009a032

Three kinetic criteria, m_Br, R (k_aqEtOH/k_AcOH)_Y, and KSIE (kinetic solvent isotope effect), are used to estimate the magnitude of the electrophilic and nucleophilic involvement of protic solvents and the occurre

Full text of DOI:10.1021/ja00009a032

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