Desulfurization of the Epidithiopiperazinedione Sirodesmin PL with Triphenylphosphine: Retention of Configuration at the Bridgehead Carbon Atoms

DOI: 10.1021/ja00354a036

Source and publish data:

Journal of the American Chemical Society p. 5402 - 5406 (1983)

Update date:2022-08-02

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Authors:

Ferezou, Jean Pierre

Quesneau-Thierry, Annik

Cesario, Michele

Pascard, Claudine

Barbier, Michel

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Article abstract of DOI:10.1021/ja00354a036

Sirodesmin PL (3), an epidithiopiperazinedione toxin produced by the fungus Phoma lingam Tode, easily reacts with triphenylphosphine to give the corresponding monosulfide 4.The stereochemical course of the reaction has been studied through chemical transf

Full text of DOI:10.1021/ja00354a036

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