Synthesis of Substituted 1,3-Dienes by the Reaction of Alkenylsulfonyl Chlorides with Olefins Catalyzed by a Ruthenium(II) Complex

DOI: 10.1246/bcsj.61.1231

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1231 - 1236 (1988)

Update date:2022-08-05

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Authors:

Kameyama, Masayuki

Shimezawa, Hiroshi

Satoh, Takeshi

Kamigata, Nobumasa

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Article abstract of DOI:10.1246/bcsj.61.1231

Alkenylsulfonyl chlorides reacted with vinylarenes in the presence of a catalytic amount of dichlorotris(triphenylphosphine)ruthenium(II) to give substituted adducts, which were dehydrochlorinated and desulfonylated successively to form substituted (E,E)-1,3-dienes in good yield.

Full text of DOI:10.1246/bcsj.61.1231

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