Synlett p. 2829 - 2832 (2017)
Update date:2022-07-31
Topics:
Gao, Ang
Liu, Xiu-Yan
Ding, Chang-Hua
Hou, Xue-Long
A palladium-catalyzed conjugate addition of arylboronic acids to α-substituted cyclic enones was developed to give α,β-disubstituted ketones with high diastereoselectivity. Mechanistic investigation showed that the high diastereoselectivity was realized through epimerization.
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