A HIGHLY REGIO- AND STEREOSELECTIVE RING-OPENING OF 2,3-EPOXY ALCOHOLS WITH TRIMETHYLSILYL AZIDE-DIETHYLALUMINIUM FLUORIDE SYSTEM

DOI: 10.1246/cl.1985.599

Source and publish data:

Chemistry Letters p. 599 - 602 (1985)

Update date:2022-08-04

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Authors:

Maruoka, Keiji

Sano, Hiromi

Yamamoto, Hisashi

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Article abstract of DOI:10.1246/cl.1985.599

A new approach to the mild and selective synthesis of 3-azidodiols has been described which involves a highly regio- and stereoselective ring-opening of 2,3-epoxy alcohols with trimethylsilyl azide and diethylaluminium fluoride.

Full text of DOI:10.1246/cl.1985.599

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