THE STEREOCHEMISTRY OF AN SE2" REACTION OF A CHIRAL DIENYLMETHYLSILANE

DOI: 10.1016/S0040-4039(01)81091-1

Source and publish data:

Tetrahedron Letters p. 5921 - 5924 (1987)

Update date:2022-08-04

Topics:

Authors:

Fleming, Ian

Kindon, Nicholas D.

Sarkar, Achintya K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81091-1

The optically active heptadienylsilane (1) reacts with isobutyraldehyde in a stereospecifically anti reaction to give predominantly (90:10) the enantiomer (3).

Full text of DOI:10.1016/S0040-4039(01)81091-1

Products guided by the article

Product name:Allyl (4E,2R,3S)-2-<(1S)-1-dimethyl(phenyl)silylethyl>-3-hydroxyhex-4-enoate

Cas No:118087-95-9

R&D Labs maybe for 118087-95-9

Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)

Contact:+86-13554447107

Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
Guangzhou Puho Pharmaceutical Technology Co. Ltd.

Contact:86-20-29848035/29848075

Address:No.166, Chaoyang East Road, Panyu District, Guangzhou City, Guangdong Province
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District

Relevant to this article

Inverting External Asymmetric Induction via Selective Energy Transfer Catalysis: A Strategy to β-Chiral Phosphonate Antipodes

Doi:10.1002/anie.201911651
(2020)
Reactions of 1,2-dehydropyrrolidin-5-one with 1,3-dienes. Synthesis of dl-gephyrotoxin 223AB

Doi:10.1139/v88-191
(1988)
The synthesis and structure of some N-(L-aspart-4-oyl)-β-D-xylopyranosylamine derivatives

Doi:10.1016/0008-6215(88)80071-5
(1988)
New Synthesis of Cyclobutane Annelated Compounds by the Use of a (1-Cyclobutenyl)triphenylphosphonium Salt

Doi:10.1021/jo00265a047
(1989)
New Molecular Hydrogen Iron(II) Complexes: Synthesis, Characterization, and Reactivity with Aryldiazonium Cations

Doi:10.1021/ja00188a021
(1989)
Intramolecularly alkylated Costa complexes: New models for coenzyme B₁₂ with a cobalt-to-ligand carbon bridge

Doi:10.1016/0040-4020(95)00132-R
(1995)

Article Doi