THE STEREOCHEMISTRY OF AN SE2" REACTION OF A CHIRAL DIENYLMETHYLSILANE

DOI: 10.1016/S0040-4039(01)81091-1

Source and publish data:

Tetrahedron Letters p. 5921 - 5924 (1987)

Update date:2022-08-04

Topics:

Authors:

Fleming, Ian

Kindon, Nicholas D.

Sarkar, Achintya K.

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Article abstract of DOI:10.1016/S0040-4039(01)81091-1

The optically active heptadienylsilane (1) reacts with isobutyraldehyde in a stereospecifically anti reaction to give predominantly (90:10) the enantiomer (3).

Full text of DOI:10.1016/S0040-4039(01)81091-1

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