STERICALLY CROWDED CYCLOHEXANES - 7. SYNTHESIS, CRYSTAL STRUCTURE, CONFORMATION AND DYNAMICS OF HEXASPIRODOCOSANE AND HEXASPIROTRICOSANE

Article abstract of DOI:10.1016/S0040-4020(01)85831-2

The synthesis, crystal structure, conformation and dynamics of hexaspiro<2.0.3.0.2.0.3.0.3.0.3.0>docosane 6 and hexaspiro<2.0.3.0.3.0.3.0.3.0.3.0>tricosane 7 are described.Both compounds adopt a chair conformation in the solid state and in solution.Their