REDUCTION SELECTIVE PAR LE BOROHYDRURE DE SODIUM D'UN GROUPE ESTER OU NITRILE DANS LES EPOXYDES GEM DISUBSTITUES PAR DEUX GROUPES ATTRACTEURS D'ELECTRONS.

DOI: 10.1016/S0040-4020(01)81701-4

Source and publish data:

Tetrahedron p. 2493 - 2502 (1988)

Update date:2022-08-04

Topics:

Authors:

Mauger, J.

Robert, A.

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Article abstract of DOI:10.1016/S0040-4020(01)81701-4

Sodium borohydride reduced the ester group of the epoxides 1 or one cyano group of 2 selectively within 5 minutes to give new hydroxy - or amino - functionalized epoxides.This unusual reduction of a cyano group has been extended to other α,α-dicyano derivatives.

Full text of DOI:10.1016/S0040-4020(01)81701-4

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