Tetrahedron Letters p. 5067 - 5070 (1984)
Update date:2022-08-02
Topics:
Tokoroyama, Takashi
Tsukamoto, Masamitsu
Iio, Hideo
The cyclization of 2-(3',4'-dimethyl-6'-trimethylsilyl-4'-hexenyl)-2-cyclohexenone with TiCl4 afforded stereospecifically 6α,7α-dimethyl-6β-vinyl-5βH-1-decalone derivate and the two-fold diastereoselection involved is reasoned in terms of orientation control and folding strain control.
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