
Journal of the Chemical Society. Chemical communications p. 142 - 143 (1990)
Update date:2022-07-30
Topics:
Ranganathan, Darshan
Singh, Girij Pal
The distribution of dipeptides upon treatment of equimolar amounts of glutamic acid, leucine, and C6H11N=C=N(CH2)3+NMe3-OSO2C6H4Me-p, in clear aqueous solution followed by N,C-protection, was found to be: Bz-Glu(γ-OMe)-Leu-OMe (72percent), Bz-Glu(α-OMe)-Glu-di-OMe (15percent), and Bz-Leu-Leu-OMe (8percent); Bz-Leu-Glu-di-OMe, Bz-Glu(α-OMe)-Leu-OMe, and Bz-Glu(γ-OMe)-Glu-di-OMe could not be detected (Bz = PhCO).
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