Bulletin of the Chemical Society of Japan p. 541 - 545 (1992)
Update date:2022-07-31
Topics: Mechanism Claisen Rearrangement Vinyl Ether Experimental Allylic
Nonoshita, Katsumasa
Maruoka, Keiji
Yamamoto, Hisashi
The organoaluminum-promoted Claisen rearrangement of allylic vinyl ethers has been mechanistically studied by two sets of experiments and the observed Z and E selectivity is best accounted for by two possible chair-like structures with R substituents axial and equatorial, respectively.
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