Cation Radical Diels-Alder Cycloadditions in Organic Synthesis of (-)-β-Selinene

DOI: 10.1021/ja00187a041

Source and publish data:

Journal of the American Chemical Society p. 1826 - 1828 (1989)

Update date:2022-08-04

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Authors:

Harirchian, Bijan

Bauld, Nathan L.

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Article abstract of DOI:10.1021/ja00187a041

The site-specific, regiospecific, and Diels-Alder periselective hole-catalyzed addition of phenyl vinyl sulfide to (S)-(-)-1-ethenyl-4-isopropenylcyclohexene is shown to provide a very direct route to the sesquiterpenoid natural product (-)-β-selinene.The

Full text of DOI:10.1021/ja00187a041

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