A new peroxide fragmentation: Efficient chemical generation of 1O2 in organic media

DOI: 10.1021/ol9018216

Source and publish data:

Organic Letters p. 4572 - 4575 (2009)

Update date:2022-08-05

Topics: Oxidation Yield Catalyst Thermolysis Efficient Photolysis Substrate Scope Solvent Effects Quenching Spectroscopic Characterization Quantum Yield Mechanistic study Radical intermediate Organic Media Chemiluminescence Reactive oxygen species (ROS)

Authors:

Ghorai, Prasanta

Dussault, Patrick H.

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Article abstract of DOI:10.1021/ol9018216

Monoactivated derivatives of 1,1-dihydroperoxides undergo an unprecedented base-promoted fragmentation to efficiently generate singlet oxygen ( ¹O₂) in anhydrous organic solvents.

Full text of DOI:10.1021/ol9018216

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