Journal of the American Chemical Society p. 1830 - 1835 (1989)
Update date:2022-08-04
Topics:
Engel, Paul S.
Wu, Wen-Xue
Benzhydryl radicals donate a hydrogen atom rapidly to the less hindered nitrogen atom of aliphatic and aromatic azo compounds, leading to the corresponding hydrazines.When the initially formed hydrazyl radical posseses a weak β-bond, it undergoes scission before receiving a second hydrogen atom.Thermolysis of benzpinacol with azocyclopropane causes a complex rearrangement to 1,5-diazaoct-5-en-1-yne (21).
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