
Journal of Organic Chemistry p. 1746 - 1747 (1993)
Update date:2022-09-26
Topics:
Beer, Robert H.
Jimenez, Jose
Drago, Russell S.
Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known α-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines.The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro- and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts.
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