Tetrahedron Letters p. 2559 - 2562 (1988)
Update date:2022-09-26
Topics: Selectivity Olefin Experimental
Moss, Robert A.
Wlostowska, Joanna
The reaction of MeOCPh with Me2C=CMe2 gives a low yield of the appropriate cyclopropane (3); however, aged olefin containing traces of the related hydroperoxide (8) or alcohol (9) impurities, selectively affords the formal O-H insertion products 7 or 4.
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