New Glycosidation Reaction 1. Combinational Use of Cp2ZrCl2-AgClO4 for Activation of Glycosyl Fluorides and Application to Highly β-Selective Glycosidation of D-Mycinose

DOI: 10.1016/0040-4039(88)85294-8

Source and publish data:

Tetrahedron Letters p. 3567 - 3570 (1988)

Update date:2022-08-05

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Authors:

Matsumoto, Takashi

Maeta, Hideki

Suzuki, Keisuke

Tsuchihashi, Gen-ichi

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Article abstract of DOI:10.1016/0040-4039(88)85294-8

The combination of Cp2MCl2-AgClO4 (M=Zr, Hf) is effective for the activation of glycosyl fluorides, which enables the highly β-selective glycoside formation of D-mycinose by performing the reaction in benzene.

Full text of DOI:10.1016/0040-4039(88)85294-8

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