Journal of the Chemical Society. Chemical communications p. 585 - 586 (1984)
Update date:2022-08-05
Topics:
Tan, Thuan Siah
Mather, Andrew N.
Procter, Garry
Davidson, Alan H.
The epoxy-allylsilane (1) was prepared by two routes and cyclised stereoselectively to give the cis-cyclopentane (9) on treatment with TiCl4; equilibration of the aldehyde corresponding to (9) gave the trans-isomer in high yield.
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