Reductive Lithiation Mediated Anionic Cyclizations and -Sigmatropic Rearrangements

DOI: 10.1021/ja00190a035

Source and publish data:

Journal of the American Chemical Society p. 2981 - 2984 (1989)

Update date:2022-07-30

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Authors:

Broka, Chris A.

Shen, Tong

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Article abstract of DOI:10.1021/ja00190a035

The anionic cyclization of several α-alkoxylithiums derived by transmetalation from their corresponding (tributylstannyl)methyl ethers is described.The resulting 2,4-disubstituted tetrahydrofurans are primarily the cis stereoisomers.It is also shown that

Full text of DOI:10.1021/ja00190a035

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