Carbon-Carbon Bond Formation by Intramolecular 1,4-Dipolar Cycloaddition: Heterocyclic Betaines generated in situ from Amides and N-substituted Amides

DOI: 10.1039/c39870000840

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 840 - 842 (1987)

Update date:2022-08-04

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Authors:

Potts, Kevin T.

Dery, Maurice O.

Kullnig, Rudolph K.

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Article abstract of DOI:10.1039/c39870000840

Reaction of benzamides and N-substituted benzamides with appropriate o-alkenyl and -alkynyl side-chains and (chlorocarbonyl)phenyl ketene gives transient anhydro-1,3-oxazinium hydroxides which readily undergo intramolecular 1,4-dipolar cycloaddition; loss

Full text of DOI:10.1039/c39870000840

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