Palladium-catalysed Hydrosulfination: Synthesis of Sulfonic Acids and S-Alkyl Alkanethiosulfonates from Alkenes, Sulfur Dioxide and Hydrogen

DOI: 10.1039/c39930001592

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1592 (1993)

Update date:2022-08-05

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Authors:

Keim, Wilhelm

Herwig, Juergen

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Article abstract of DOI:10.1039/c39930001592

S-Alkyl alkanethiosulfonates and sulfonic acids can easily be synthesized from sulfur dioxide, alkenes, hydrogen and a cationic palladium(II)-diphosphine complex like 2 1 , at temperatures above the ceiling temperature of the SO2-alkene copolymer.

Full text of DOI:10.1039/c39930001592

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