Journal of the Chemical Society. Perkin transactions II p. 1965 - 1968 (1990)
Update date:2022-08-02
Topics:
Migita, Catharina T.
Chaki, Satoshi
Nakayama, Masaharu
Ogura, Kotaro
Spin trapping of the gas-phase photoreaction system methane-ammonia-water and the related methylamine-water-oxygen system have been performed using α-phenyl-N-t-butylnitrone (PBN).In the former case, methoxyl and aminomethyl radicals were trapped and in the latter, nitromethyl radical was trapped under a higher molar fraction of oxygen and aminomethyl radical was trapped under a lower and zero molar fraction of oxygen.The trapped radicals were identified by comparison of their ESR spectroscopic parameters with those of synthetically-obtained homologues.
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