Angewandte Chemie - International Edition p. 11651 - 11655 (2013)
Update date:2022-08-03
Topics:
Lemke, Marie-Kristin
Schwab, Pia
Fischer, Petra
Tischer, Sandra
Witt, Morris
Noehringer, Laurence
Rogachev, Victor
Jaeger, Anne
Kataeva, Olga
Froehlich, Roland
Metz, Peter
A surprisingly selective, non-enzymatic kinetic resolution of readily available, racemic β-chiral ketones enabled the title process, which was applied to a rapid synthesis of several bioactive flavanones in virtually enantiopure form (see scheme; MOM=methoxymethyl, Ts=p-toluenesulfonyl). Copyright
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