Journal of the Chemical Society. Perkin transactions II p. 351 - 354 (1988)
Update date:2022-07-31
Topics:
Carr, Graham
Dean, Cristopher
Whittaker, David
A number of terpenoid bicyclic ethers have been prepared by cyclisation of suitable precursors in fluorosulphuric acid-sulphur dioxide.The products are formed under a mixture of thermodynamic and kinetic control, and five-, and six-, and seven-membered-ring ethers are obtained.Both primary and secondary alcohols have been cyclised by attack of the hydroxy group on carbocation centres generated by protonation of alkenes or ionisation of tertiary alcohols; tertiary alcohols ionise too readily to provide an etheral oxygen atom.Reaction of the unsaturated secondary alcohol dihydrocarveol (2) with antimony pentafluoride in sulphur dioxide gives the ether by a reaction which may not involve a carbocation, and hence may be suitable for ether formation from substrates which rearrange readily in acids.
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